Presenter Information

John C. JohnsonFollow

Clay-Based Heterogeneous Green Catalysts for the Epoxidation Reaction

Location

Poster Session 1 (Henderson Library)

Session Format

Poster Presentation

Your Campus

Statesboro Campus- Henderson Library, April 20th

Academic Unit

Department of Chemistry

Research Area Topic:

Natural & Physical Sciences - Chemistry

Co-Presenters and Faculty Mentors or Advisors

Miles San Soucie

Shainaz Landge

Abstract

Heterogeneous catalysts are commonly used in the chemical industry and have many implications in green chemistry. Utilizing heterogeneous catalysts for oxidation reactions enables the catalyst to be filtered out of the solution for reuse, also making separation of the product more efficient. This project's goal is to synthesize transition metal based heterogeneous catalysts supported by halloysite nanotubes (HNTs) for selective epoxidation reactions. HNTs are a hollow and tubular form of clay, and are much cheaper than carbon nanotubes as they are abundantly found in nature. The first heterogeneous catalyst synthesized in the lab will consist of (3-glycidyloxypropyl)trimethoxysilane (GOPS) bound to the HNTs to provide a reactive functional group handle for the transition metal containing ligand to be attached. Alizarin red’s vanadium complex will be used as the first transition metal containing ligand to be supported by the HNTs. Derivatives of the catalyst will be synthesized using various transition metals containing ligand complexes. General epoxidation reactions with cyclohexene will be tested using the novel catalyst to evaluate its catalytic activity and reusability.

Program Description

Heterogenous catalysts supported by halloysite nanotubes for selective epoxidation reactions.

Creative Commons License

Creative Commons License
This work is licensed under a Creative Commons Attribution 4.0 License.

Presentation Type and Release Option

Presentation (File Not Available for Download)

Start Date

4-20-2022 10:00 AM

End Date

4-20-2022 11:30 AM

This document is currently not available here.

Share

COinS
 
Apr 20th, 10:00 AM Apr 20th, 11:30 AM

Clay-Based Heterogeneous Green Catalysts for the Epoxidation Reaction

Poster Session 1 (Henderson Library)

Heterogeneous catalysts are commonly used in the chemical industry and have many implications in green chemistry. Utilizing heterogeneous catalysts for oxidation reactions enables the catalyst to be filtered out of the solution for reuse, also making separation of the product more efficient. This project's goal is to synthesize transition metal based heterogeneous catalysts supported by halloysite nanotubes (HNTs) for selective epoxidation reactions. HNTs are a hollow and tubular form of clay, and are much cheaper than carbon nanotubes as they are abundantly found in nature. The first heterogeneous catalyst synthesized in the lab will consist of (3-glycidyloxypropyl)trimethoxysilane (GOPS) bound to the HNTs to provide a reactive functional group handle for the transition metal containing ligand to be attached. Alizarin red’s vanadium complex will be used as the first transition metal containing ligand to be supported by the HNTs. Derivatives of the catalyst will be synthesized using various transition metals containing ligand complexes. General epoxidation reactions with cyclohexene will be tested using the novel catalyst to evaluate its catalytic activity and reusability.