Term of Award

Summer 2024

Degree Name

Master of Science, Civil Engineering

Document Type and Release Option

Thesis (open access)

Copyright Statement / License for Reuse

Creative Commons License
This work is licensed under a Creative Commons Attribution 4.0 License.

Department

Department of Civil Engineering and Construction

Committee Chair

Francisco Cubas Suazo

Committee Member 1

L. Stetson Rowles

Committee Member 2

Rocio L. Perez

Abstract

Over the past few decades, an enormous number of resources have been allocated to reduce the amount of phosphorus (P) entering the environment from both point and non-point sources. Nevertheless, the decrease in external P loading has not always resulted in a simultaneous decrease in the occurrence of harmful algal blooms (HABs) in waters contaminated with phosphorus. A two-part study is currently being conducted to investigate and measure the role of legacy recalcitrant P forms in the overall pool of soluble reactive phosphorus (SRP). However, the objective of this particular study is to evaluate the potential of Organic Phosphorus (PO) mineralization towards the SRP pool. Results from field data and lab-scaled experiments, showed that under both initial low and high OP levels sediments from streams subject to legacy P loadings released OP and organic P when subject to different environments. The total phosphorus (TP) levels at the Occoquan and RAC sample sites were primarily influenced by redox reactions and organic phosphorus associated with iron-bound sediments. However, in the Ogeechee River sample stations, the regulation of TP was not just affected by OP because there was no presence of Fe-bound OP, but also by organic P. Furthermore, while anaerobic conditions improve the overall process of PO mineralization, it is evident that the OP/TP ratio also changes when exposed to aerobic environments. Thus, results from this study invariably indicate that recalcitrant organic P forms are important sources for OP as microorganisms are required to mineralize organic P under low dissolved OP conditions.

Research Data and Supplementary Material

No

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