Term of Award
Spring 2018
Degree Name
Master of Science in Applied Engineering (M.S.A.E.)
Document Type and Release Option
Thesis (restricted to Georgia Southern)
Copyright Statement / License for Reuse
This work is licensed under a Creative Commons Attribution 4.0 License.
Department
Department of Mechanical Engineering
Committee Chair
Molina Gustavo
Committee Member 1
Valentin Soloiu
Committee Member 2
Rahman Mosfequr
Abstract
The use of biodiesels has been growing as they can replace traditional fossil fuel while being produced from different feedstock and being a renewable source of energy. But the chemical composition of biodiesel is substantially different than that of the mineral biodiesel they replace, and each feedstock biodiesel has a different breakdown of components (mainly Methyl Esters from esterification of the fatty acids of the oil feedstock).Use of biodiesels in internal combustion engines leads to oil dilution because unburned biodiesel is being scrapped to the engine oil pan, and its lower volatility and early aging (as compared to those of mineral diesel fuel) can enhance degradation of oil lubricity. This research is presented on the wear and friction effects when Methyl Esters typical in the breakdown of biodiesels are mixed with SAE 15W40 mineral oil typically used in diesel engines: Tribometer studies are carried out for mixtures of known percentages of such Methyl Esters in mineral engine oil. Experimental results show that the employed methodologies and instruments used are suitable to study the research problem and those of evaluating how the breakdown of biodiesel may explain the tribological behavior of their mixtures with oil. The specific results also suggest that Methyl Oleate and Methyl Laurate lead to the lowest wear of all the typical biodiesel Methyl Ester components. Also, the higher fraction of Methyl Oleate and a lower fraction of Methyl Linoleate in Peanut oil biodiesel plays a role in providing good lubricity performance in Peanut oil biodiesel as compared to Soybean oil biodiesel.
Recommended Citation
[1] S. M. Shanta, "Investigations of the tribological effects of engine oil dilution by vegetable and animal fat feedstock biodiesel on selected surfaces," 2011. [2] J. Hu, Z. Du, C. Li, and E. Min, "Study on the lubrication properties of biodiesel as fuel lubricity enhancers," Fuel, vol. 84, pp. 1601-1606, 2005. [3] K. Wadumesthrige, M. Ara, S. O. Salley, and K. S. Ng, "Investigation of lubricity characteristics of biodiesel in petroleum and synthetic fuel," Energy & Fuels, vol. 23, pp. 2229-2234, 2009. [4] E. Alptekin and M. Canakci, "Determination of the density and the viscositiesT of biodiesel–diesel fuel blends," Renewable energy, vol. 33, pp. 2623-2630, 2008. [5] G. Knothe and K. R. Steidley, "Kinematic viscosity of biodiesel fuel components and related compounds. Influence of compound structure and comparison to petrodiesel fuel components," Fuel, vol. 84, pp. 1059-1065, 2005. [6] M. Sulek, A. Kulczycki, and A. Malysa, "Assessment of lubricity of compositions of fuel oil with biocomponents derived from rape-seed," Wear, vol. 268, pp. 104-108, 2010. [7] M. Lapuerta, J. Sánchez-Valdepeñas, D. Bolonio, and E. Sukjit, "Effect of fatty acid composition of methyl and ethyl esters on the lubricity at different humidities," Fuel, vol. 184, pp. 202-210, 2016. [8] S. Hamdan, W. Chong, J.-H. Ng, C. Chong, and S. Rajoo, "A study of the tribological impact of biodiesel dilution on engine lubricant properties," Process Safety and Environmental Protection, vol. 112, pp. 288-297, 2017. [9] M. Fazal, A. Haseeb, and H. Masjuki, "Investigation of friction and wear characteristics of palm biodiesel," Energy conversion and management, vol. 67, pp. 251-256, 2013. [10] M. Mosarof, M. Kalam, H. Masjuki, A. Alabdulkarem, M. Habibullah, A. Arslan, et al., "Assessment of friction and wear characteristics of Calophyllum inophyllum and palm biodiesel," Industrial Crops and Products, vol. 83, pp. 470-483, 2016. [11] J. M. Martin, C. Matta, M.-I. D. B. Bouchet, C. Forest, T. Le Mogne, T. Dubois, et al., "Mechanism of friction reduction of unsaturated fatty acids as additives in diesel fuels," Friction, vol. 1, pp. 252-258, 2013. [12] M. I. D. B. Bouchet, J. M. Martin, C. Forest, T. le Mogne, M. Mazarin, J. Avila, et al., "Tribochemistry of unsaturated fatty acids as friction modifiers in (bio) diesel fuel," RSC Advances, vol. 7, pp. 33120-33131, 2017. [13] S. Hamdan, W. Chong, J.-H. Ng, M. Ghazali, and R. Wood, "Influence of fatty acid methyl ester composition on tribological properties of vegetable oils and duck fat derived biodiesel," Tribology International, vol. 113, pp. 76-82, 2017. [14] J. Encinar, N. Sánchez, G. Martínez, and L. García, "Study of biodiesel production from animal fats with high free fatty acid content," Bioresource Technology, vol. 102, pp. 10907-10914, 2011. [15] M. A. H. Altaie, R. B. Janius, U. Rashid, Y. H. T. Yap, R. Yunus, and R. Zakaria, "Cold flow and fuel properties of methyl oleate and palm-oil methyl ester blends," Fuel, vol. 160, pp. 238-244, 2015. [16] M. J. Ramos, C. M. Fernández, A. Casas, L. Rodríguez, and Á. Pérez, "Influence of fatty acid composition of raw materials on biodiesel properties," Bioresource technology, vol. 100, pp. 261-268, 2009. [17] J. W. Goodrum and D. P. Geller, "Influence of fatty acid methyl esters from hydroxylated vegetable oils on diesel fuel lubricity," Bioresource Technology, vol. 96, pp. 851-855, 2005. [18] D. P. Geller and J. W. Goodrum, "Effects of specific fatty acid methyl esters on diesel fuel lubricity," Fuel, vol. 83, pp. 2351-2356, 2004. [19] G. Martínez, N. Sánchez, J. Encinar, and J. González, "Fuel properties of biodiesel from vegetable oils and oil mixtures. Influence of methyl esters distribution," Biomass and Bioenergy, vol. 63, pp. 22-32, 2014. [20] M. Hernandez-Cruz, R. Meza-Gordillo, B. Torrestiana-Sanchez, A. Rosales-Quintero, L. Ventura-Canseco, and J. Castanon-Gonzales, "Chicken fat and biodiesel viscosity modification with additives for the formulation of biolubricants," Fuel, vol. 198, pp. 42-48, 2017. [21] B. R. Moser, R. L. Evangelista, and G. Jham, "Fuel properties of Brassica juncea oil methyl esters blended with ultra-low sulfur diesel fuel," Renewable Energy, vol. 78, pp. 82-88, 2015. [22] N. Nisar, S. Mehmood, H. Nisar, S. Jamil, Z. Ahmad, N. Ghani, et al., "Brassicaceae family oil methyl esters blended with ultra-low sulphur diesel fuel (ULSD): Comparison of fuel properties with fuel standards," Renewable Energy, vol. 117, pp. 393-403, 2018. [23] G. Knothe, "Improving biodiesel fuel properties by modifying fatty ester composition," Energy & Environmental Science, vol. 2, pp. 759-766, 2009. [24] F. Yasar, S. Altun, and H. Adin, "Fuel properties of biodiesels produced from blends of canola oil and animal tallow," Energy Educ Sci Technol Part A, vol. 27, pp. 199-208, 2011. [25] G. Knothe, "Dependence of biodiesel fuel properties on the structure of fatty acid alkyl esters," Fuel processing technology, vol. 86, pp. 1059-1070, 2005. [26] D. Uy, R. J. Zdrodowski, A. E. O'neill, S. J. Simko, A. K. Gangopadhyay, M. Morcos, et al., "Comparison of the effects of biodiesel and mineral diesel fuel dilution on aged engine oil properties," Tribology Transactions, vol. 54, pp. 749-763, 2011. [27] V. Bučinskas and R. Subačius, "Tribological properties of biodiesel fuel and its mixtures with diesel fuel," 2009. [28] M. A. V. da Silva, B. L. G. Ferreira, L. G. da Costa Marques, A. L. S. Murta, and M. A. V. de Freitas, "Comparative study of NOx emissions of biodiesel-diesel blends from soybean, palm and waste frying oils using methyl and ethyl transesterification routes," Fuel, vol. 194, pp. 144-156, 2017. [29] G. Knothe, "“Designer” biodiesel: optimizing fatty ester composition to improve fuel properties," Energy & Fuels, vol. 22, pp. 1358-1364, 2008. [30] M. M. Maru, R. M. Trommer, F. A. Almeida, R. F. Silva, and C. A. Achete, "Assessment of the lubricant behaviour of biodiesel fuels using Stribeck curves," Fuel processing technology, vol. 116, pp. 130-134, 2013. [31] F. Y. H. A. S. Aslan and Ş. Altun, "Comparing the lubricity of different biodiesel fuels," 2011. [32] F. Y. H. A. S. Aslan and Ş. Altun, "Comparing the lubricity of different biodiesel fuels." [33] L. Schumacher and S. Howell, "Lubricating qualities of biodiesel and biodiesel blends," Western Regional Biomass Energy Program, Reno, NV (United States)1994. [34] "Mobil Delvac 15W40 Engine oil." [35] J. Rick, "Down to earth energy," Atlanta2017. [36] R. G. Bayer, "Mechanical wear prediction and prevention," Marcel! Dekker, Inc, P. O. Box 5005, Monticello, NY 12701-5185, USA, 1994. 657, 1994. [37] A. Zmitrowicz, "Wear patterns and laws of wear–a review," Journal of theoretical and applied mechanics, vol. 44, pp. 219-253, 2006. [38] R. C. Bayer, "Mechanical Wear Prediction and Prevention," ed, 1997. [39] T. d. O. Macedo, R. G. Pereira, J. M. Pardal, A. S. Soares, and V. d. J. Lameira, "Viscosity of vegetable oils and biodiesel and energy generation," World Academy of Science, Engineering and Technology, vol. 77, pp. 173-178, 2013. [40] R. A. Al-Samarai, K. R. A. Haftirman, and Y. Al-Douri, "Evaluate the effects of various surface roughness on the tribological characteristics under dry and lubricated conditions for Al-Si alloy," Journal of Surface Engineered Materials and Advanced Technology, vol. 2, p. 167, 2012. [41] H. L. Fang, S. D. Whitacre, E. S. Yamaguchi, and M. Boons, "Biodiesel impact on wear protection of engine oils," SAE Technical Paper 0148-7191, 2007.
Research Data and Supplementary Material
No