Term of Award
Fall 2013
Degree Name
Master of Science in Applied Engineering (M.S.A.E.)
Document Type and Release Option
Thesis (restricted to Georgia Southern)
Department
Department of Mechanical Engineering
Committee Chair
Shaowen Xu
Committee Member 1
John DiCesare
Committee Member 2
Don McLemore
Committee Member 3
Mujibur Khan
Committee Member 3 Email
mkhan@georgiasouthern.edu
Abstract
A novel approach was taken to achieve sidewall functionalization by reacting carbon nanotubes with the Grignard reagents phenylmagnesium and styrenylmagnesium bromides. Covalent attachment to the sidewalls was investigated using sedimentation studies and thermogravimetric analysis (TGA). Nanotubes were also characterized using scanning electron microscopy. Polystyrene/Multiwalled Carbon Nanotube (PS/MWCNT) nanocomposites were prepared via in-situ polymerization utilizing thermal bulk polymerization. The Young’s modulus is shown to increase by 4% compared to neat polystyrene by incorporating 0.1% functionalized MWCNTs. Elongation at break is shown to increase by more than 100% compared to neat polystyrene for functionalized MWCNT loading of 0.1wt%. Increases in both modulus and strength were also observed with increased nanotube loadings. The glass transition temperatures of the composites are shown to increase with the addition of functionalized MWCNTs.
Recommended Citation
Long, Christopher, "The Effect of Functionalized Multiwalled Carbon Nanotubes on The Mechanical And Rheological Properties of Polystyrene/Nanotube Composites" (2013). Electronic Theses and Dissertations. 898.
https://digitalcommons.georgiasouthern.edu/etd/898
